无氟超疏水材料进展

没空编译了,小伙伴们看下图就懂了,这个超疏水和超亲水材料是如何实现的,看文献去吧(下面这个是氧化铝纳米颗粒)

无氟超疏水材料

参考文献: Wafaa Al-Shatty et al, Tunable Surface Properties of Aluminum Oxide Nanoparticles from Highly Hydrophobic to Highly Hydrophilic, ACS Omega (2017). DOI: 10.1021/acsomega.7b00279

The formation of materials with tunable wettability is important for applications ranging from antifouling to waterproofing surfaces. We report the use of various low-cost and nonhazardous hydrocarbon materials to tune the surface properties of aluminum oxide nanoparticles (NPs) from superhydrophilic to superhydrophobic through covalent functionalization. The hydrocarbon surfaces are compared with a fluorinated surface for wettability and surface energy properties. The role of NPs’ hydrophobicity on their dynamic interfacial behavior at the oil–water interface and their ability to form stable emulsions is also explored. The spray-coated NPs provide textured surfaces (regardless of functionality), with water contact angles (θ) of 10–150° based on their surface functionality. The superhydrophobic NPs are able to reduce the interfacial tension of various oil–water interfaces by behaving as surfactants.

https://pubs.acs.org/doi/abs/10.1021/acsomega.7b00279

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